1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.1]decane 7-oxide triiodide

1-Methyl-1-azonia-3,5-diaza-7-phospha­tricyclo­[3.3.1.1]decane 7-oxide triiodide

The title compound, C(7)H(15)N(3)OP(+)·I(3) (-), is a derivative of the well known water-soluble amino-phosphine 1,3,5-triaza-7-phosphaadamantane (PTA). The crystal structure is composed of a cage-like 1-methyl-1-azonia-3,5-diaza-7-phospha-tricyclo-[3.3.1.1]decane 7-oxide cation and a triiodide anion. The N-methyl-ation of the PTA cage results in a slight elongation of the corresponding C-N bon...

1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo­[3.3.1.13,7]decane tetra­fluoro­borate

The title compound, C(7)H(15)N(3)P(+)·BF(4) (-) or [PTA-Me][BF(4)], is the N-methyl-ated derivative of the well known water-soluble amino-phosphine 1,3,5-triaza-7-phosphaadamantane (PTA). The asymmetric unit consists of a cage-like cation [PTA-Me](+) and a disordered tetra-fluoro-borate anion; two F atoms are disordered equally over two sites. A network of weak inter-molecular C-H⋯F hydrogen bo...

Editorial Volume 7, Issue 1

JALDA, therefore, would like to show inclination towards the view that the reality of the world is not a fixed entity standing out there to be measured by our pre-fabricated ‘scientific’ instruments. In line with Haghshenas’ argumentation, not only can theories and instruments shrink to ornamental entities but also they can turn into what Karl Popper calls pseudo-science, knowledge of an ‘ideol...

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Cover Vol.7, No.1, February 2010